Are you already in the UK? If so, what visa do you have?
How did your brother obtain uk citizenship?
Thanks for your patience.
Unfortunately, you are not regarded as a family member of your brother for the purpose of the immigration rules.
This means that you cannot apply on the basis that your brother is a UK citizen.
The only possible way that this would be conceivably possible would be if both you are your wife were dependent on him financially and also to carry out day to day tasks (washing, cleaning etc). In these circumstances you might be able to apply for an adult dependent relatives visa. However, the fact that your wife has been working and that you have recently been capable of living as an independent family unit indicates that this would not be possible.
I am afraid that your only option would appear to be for your wife to attempt to find a new sponsor willing to offer her a job for tier 2 purposes.I am sorry that I could not have better news for you.
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