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Hi.Unless either of you or your wife were born before 6 April 1935, you won't qualify for the married couples' allowance which can be switched between spouses.As for the personal allowance, as of now any part of the allowance which is not used by your wife cannot be transferred to you I'm afraid. However, from 6 April 2015, it will be possible for up to £1,050 of one spouse's personal allowance to be transferred to the other. You can read about that here.I hope this helps but let me know if you have any further questions.