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Yes, this is possible as long as the right procedure is followed e.g. giving of notice of intention to marry.
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in Awuku v SSHD  EWCA Civ 178, the court of appeal decided that if a proxy marriage complies with the law of the land in which it is celebrated it will be recognised in England and Wales.
So, if your marriage is lawful under Ghanaian law, it would be valid in the UK.
Once you get married, you may then both apply under the EU Settlement Scheme: https://www.gov.uk/settled-status-eu-citizens-families/applying-for-settled-status
There is no risk involved.
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It overrides your asylum application and once granted, you will no longer be an asylum seeker.