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Good day your question has been forwarded to me to see if I may be able to assist.
I will be candid in saying that his situation is a very difficult one. You will find that because he is not legally in the UK you would not be able to add him to your visa as a dependent. This situation would not change by virtue of you guys being married. The only resolution I could propose is for you to apply for him if you were to acquire british citizenship. Alternatively he may apply if you both were to have a child who was a british citizen.
Both thse scenarios would allot him to apply on human rights grounds to remain in the UK.
Save that, I do not see away forward for him
Hope this helps. Kindly let me know if I may further assist.
ALl the best