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why do you think you have silicone absorbed into your skin?
silicone water proofing sprays for your shoes would not get absorbed into your skin.
you should not be using solvents and alcohol on your skin. this is what caused your skin to be dry.
if your water is hard, with minerals this can cause you not to be able to wash off soaps on from your hands.
you may need a water softening system for your water.
you should use some moisturizers for your skin for now.
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