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Yes if going to work abroad full-time for at least one full tax year.
Fill in form P85 and send it to HMRC. Include Parts 2 and 3 of your P45 form - get these from your employer
Send a P85 and a tax return if you’re going to be working full-time for a UK-based employer for at least one full tax year.
You will be taxed in Portugal
Residents in Portugal for tax purposes are taxed on their worldwide income at progressive rates varying from 14.5% to 48%
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