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Here is the guidance from the Gov UK Web Site:
'If you do not have a V5C or new keeper slip
If you’re the current keeper, you must apply for a new V5C and tax your vehicle at a Post Office. This costs £25 and it can take 4 to 6 weeks to get the new V5C.' If you have the 11 digit reference number from the V5C you can pay on line to tax your vehicle. The procedure is here: