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In Payroll, they split your basic rate band over the year and you start getting taxed at higher rate from Month 1.
Yes, you have paid the right tax. you can recheck here:
UK Salary Tax Calculator 2021 / 2022: Calculate my take home pay (listentotaxman.com)
Yes, they'll be using your Scottish tax code
In payroll, they divide your total basic rate band over 12 months which is £3,333 per month. If you get salary above £3,333, it will be taxed at 40%