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As a UK VAT registered business importing goods to the UK, you will be able to account for import VAT on your VAT return, rather than paying import VAT on or soon after the time that the goods arrive at the UK border.
VAT registered UK businesses continue to be able to zero-rate sales of goods to EU businesses. EU member states will treat goods entering the EU from the UK in the same way as goods entering from other non-EU countries. This means import VAT and any customs duties (tariffs) are due when the goods arrive in the EU.
Yes, you would need to be registered both in the UK and in the EU country. Note if you keep your goods in EU and supply to India from there, it would be outside the scope of UK VAT. The paperwork will be the same wherever you export from so best not let it be a deciding factor.
You can leave the goods in private customs warehouse but you’ll need to make a customs declaration to remove the goods or declare them to another procedure.
If you move your goods to another customs procedure such as you re-export the goods directly from the customs warehouse, no charges will be due.